Download Catalytic Activation of Carbon Dioxide by William M. Ayers PDF

By William M. Ayers

content material: resources and economics of carbon dioxide / Sol J. Barer and Kenneth M. Stern --
Carbon dioxide equilibria / James N. Butler --
Coordination of carbon dioxide to nickel : an alternate theoretical version / R.P. Messmer and H.-J. Freund --
Metal-induced alterations of carbon dioxide / Donald J. Darensbourg, Christopher G. Bauch, and Cesar Ovalles --
Use of stoichiometric reactions within the layout of redox catalyst for carbon dioxide relief / Daniel L. DuBois and Alex Miedaner --
Electrocatalytic carbon dioxide aid / B. Patrick Sullivan, Mitchell R.M. Bruce, Terrence R. O'Toole, C. Mark Bolinger, Elise Megehee, Holden Thorp, and Thomas J. Meyer --
Enzymatic activation of carbon dioxide / Leland C. Allen --
Adsorptive and catalytic homes of carbon monoxide and carbon dioxide over supported steel oxides / D.G. Rethwisch and J.A. Dumesic --
Adsorption and response of carbon dioxide on zirconium dioxide / Ronald G. Silver, Nancy B. Jackson, and John G. Ekerdt --
impression of potassium at the hydrogenation of carbon monoxide and carbon dioxide over supported Rh catalysts / S.D. Worley and C.H. Dai --
Carbon dioxide relief with an electrical box assisted hydrogen insertion response / W.M. Ayers and M. Farley --
Electrochemical relief of aqueous carbon dioxide at electroplated Ru electrodes : investigations towards the mechanism of methane formation / Karl W. Frese, Jr. and David P. Summers --
Electrochemical reviews of carbon dioxide and sodium formate in aqueous suggestions / M.H. Miles and A.N. Fletcher --
Electrochemical activation of carbon dioxide / okay. Chandrasekaran and J. O'M. Bockris.

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Chem. S o c , i n p r e s s ) . I n s o l u t i o n t h e s e s p e c i e s a r e e x t r e m e l y CO l a b i l e , decomposing r e a d i l y t o W„(CO) ( y - 0 R ) ~ i n t h e absence o f a CO atmosphere ( 3 5 ) . Treatment o f [Et„N][W(CO) 0R] w i t h C 0 i n THF under m i l d c o n d i t i o n s (< 1 atmosphere C 0 a t ambient temperature) r e s u l t s i n r a p i d p r o d u c t i o n o f W(CO) 0C(0)0R~, t h e product o f C 0 i n s e r t i o n i n t o the W-OR bond. The t u n g s t e n p e n t a c a r b o n y l a r y l carbonate complex was c h a r a c t e r i z e d by I R , *H, and C ΝMR s p e c t r o s c o p i e s .

Ikaraski, T. Chem. Economy & Eng. Rev. 1980, 12, 31 17. Darensbourg, D. ; Rokicki, A. Organometallics 1982, 1, 1685. 18. Slater, S. ; Schumann, B. ; Darensbourg, M. Organometallics 1982, 1, 1662. 19. Darensbourg, D. J . ; Darensbourg, M. Y. J. Am. Chem. Soc. 1981, 103, 3223. 20. Kao, S. ; Darensbourg, M. ; Schenck, W. Organometallics 1984, 3, 871. 21. Darensbourg, D. J . ; Waller, J. Organometallics 1985 2, 1285. 22. Darensbourg, D. J . ; Kudaroski, R. J. Am. Chem. Soc. 1984, 106, 3672. 23. Darensbourg, D.

Chem. 1983, 22, 129. ch004 40 10. Sneeden, R. P. A. ; Stone, F. G. ; Abel, E. ; Pergamon Press: Oxford, 1982; Vol. 225. 11. ; Yamamoto, A. : Toyko, Japan, 1982, p 79. 12. Darensbourg, D. J . ; Ovalles, C. Chem. Tech. 1985, 15, 636. 13. Chem. Eng. News, 1985, 63, 10. 14. Czoukowski, M. ; Bayne, A. R. Hydrocarbon Process. 1980, 59, 103. 15. Leonard, J. D. S. Patent 4 299 981 (1981). 16. Ikaraski, T. Chem. Economy & Eng. Rev. 1980, 12, 31 17. Darensbourg, D. ; Rokicki, A. Organometallics 1982, 1, 1685.

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